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Raiders assigned to commercial plots

If you don't have NukaWorld, this is normal. As long as they are correctly assigned to the markers, your character should speak and say something like "Show me what kind of armor you have." and just open the Barter menu.

If you do have NukaWorld, or the barter menu isn't coming up, try re-assigning them temporarily to a vanilla workshop object, like a crop or guard post (you can just build one temporarily). Then assign them back to the Commercial plot and try again. Be sure to talk to them during business hours, which should be from about 7 AM until about 8 PM.
 
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